High pressure chemistry : synthetic, mechanistic, and supercritical applications / edited by Rudi van Eldik and Frank-Gerrit Klärner
Contributor(s): Van Eldik, R | Klärner, Frank-Gerrit.Material type: Book; Format: print Publisher: Weinheim : Wiley-VCH, 2002Description: XVI, 458 p. ; 25 cm.ISBN: 3-527-30404-5.Subject(s): Química Física | Reacciones químicas
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It is a basic law of chemistry that pressure influences reactions. Thus, high-pressure reactions are no longer a rarity in chemistry today, but rather are indispensable tools - whether for innovative syntheses, new products or for explaining reaction mechanisms. The expert editors, Rudi van Eldik and Frank-Gerrit Klarner, provide a comprehensive overview of this fascinating field, ranging from the influence of high pressure on organic and inorganic reactions, via concrete applications in synthesis for metal catalytic and stereoselective processes right up to the use of supercritical liquids. Written by renowned experts, this volume contains a wealth of vital and practical information, for both newcomers to the field as well as experienced high-pressure chemists. Whether in academia or industry, this book belongs on the shelf of every chemist concerned with high-pressure chemistry either now or in the future.
Índice: BASIC PRINCIPLES. Effect of Pressure on Inorganic and MetalorganicReactions : Introduction and Mechanistic Applications (R. van Eldik and C.D. Hubbard). The Effect of Pressure on Organic Reactions: Basic Principles and Mechanistic Applications (F. Wurche and F--G Klarner). High--Pressure Kinetics and Highly Viscous Media (T. Asano). MECHANISTIC AND SYNTHETIC APPLICATIONS OF HIGH PRESSURE. Water Exchange on Metal Ions: The Effect of Pressure (L. Helm and A.E. Merbach). Insights into Solution Chemistry from High Pressure Electrochemistry (T.W. Swaddle). Pressure Effects on the Phtoreactions of Transition Me... Etc.