Vapor-liquid equilibrium data collection : aqueous-organic systems / J. Gmehling, U. Onken

Por: Gmehling, JColaborador(es): Onken, UTipo de material: TextoTextoSeries Chemistry data series. 1 ; ; 1Detalles de publicación: Frankfurt : Dechema, 1991 Edición: 2nd., 3rd. printingDescripción: LXXXIV, 698 p. : il., gráf. ; 25 cmISBN: 3-926959-30-4Tema(s): Equilibrio químico | Equilibrio líquido-vapor | Procesos químicos
Contenidos:
Vol. I, part 1
Resumen: Volume I is a comprehensive collection of vapor-liquid equilibrium data with more than 16.000 isothermal or isobaric data sets for binary and multicomponent mixtures at low to moderate pressures. The first part covers aqueous systems. Other parts deal with mixtures of organic compounds. Fundamentals and methods of vapor-liquid equilibrium calculations are outlined in the general introduction to Part 1. The constants of the UNIQUAC, NRTL, Wilson, van Laar, and Margules correlations are given together with the deviations between the experimental values and the values obtained by calculation. For each system the best correlation method is used to show graphically the fit to experimental data. Activity coefficients at infinite dilution are also given. Thermodynamic consistency is tested by two methods. Recommended Wilson, NRTL, and UNIQUAC parameters are listed for those systems for which at least two data sets exist fulfilling the consistency tests. Vapor pressure constants (Antoine equation) for the pure compounds with their regions of validity are given.
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Vol. I, part 1

Volume I is a comprehensive collection of vapor-liquid equilibrium data with more than 16.000 isothermal or isobaric data sets for binary and multicomponent mixtures at low to moderate pressures. The first part covers aqueous systems. Other parts deal with mixtures of organic compounds. Fundamentals and methods of vapor-liquid equilibrium calculations are outlined in the general introduction to Part 1. The constants of the UNIQUAC, NRTL, Wilson, van Laar, and Margules correlations are given together with the deviations between the experimental values and the values obtained by calculation. For each system the best correlation method is used to show graphically the fit to experimental data. Activity coefficients at infinite dilution are also given. Thermodynamic consistency is tested by two methods. Recommended Wilson, NRTL, and UNIQUAC parameters are listed for those systems for which at least two data sets exist fulfilling the consistency tests. Vapor pressure constants (Antoine equation) for the pure compounds with their regions of validity are given.

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